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Tetrapotassium Pyrophosphate (TKPP) Supplier

A water-soluble potassium phosphate builder and dispersant — preferred over TSPP in liquid cleaning formulations due to its higher solubility and compatibility with potassium-based surfactant systems.

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Quick Specs

CAS No.7320-34-5
Molecular FormulaK₄P₂O₇
AppearanceWhite crystalline powder or granules
Active Content (P₂O₅)~42–43%
pH (1% solution)~10.5–11
Solubility in Water~185 g/L at 25°C
Molecular Weight330.3 g/mol
GradeTechnical / Food

What Is Tetrapotassium Pyrophosphate?

Tetrapotassium pyrophosphate (TKPP) is the potassium salt of pyrophosphoric acid (diphosphoric acid), containing four potassium cations and the P₂O₇⁴⁻ pyrophosphate anion. It is the potassium analogue of tetrasodium pyrophosphate (TSPP), and shares its builder and dispersant functions but offers significantly higher aqueous solubility (~185 g/L vs ~30 g/L for TSPP at 25°C). This makes TKPP the preferred pyrophosphate builder for liquid detergent and liquid cleaning product formulations, where the low solubility of TSPP would cause precipitation or instability.

Cleaning Functions

TKPP functions as a chelating agent that sequesters calcium and magnesium ions in wash water, preventing their precipitation with anionic surfactants and maintaining surfactant efficiency in hard water conditions. It also disperses and peptises clay, protein, and pigment soils in the wash liquor. In liquid hand dishwash products, TKPP improves soil suspension and hard water tolerance. In industrial liquid degreasers and alkaline cleaners, it contributes both builder activity and mild alkalinity. TKPP is also used in the dairy and food processing industry as a sequestrant in equipment CIP formulations.

Supply and Formulation Advice

Terracore Chemicals supplies technical-grade TKPP in 25 kg bags and food-grade TKPP for food processing applications. We advise formulators on TKPP vs TSPP selection criteria for specific formulations and on compatibility with anionic and nonionic surfactant systems at target concentrations.

Applications

  • Liquid laundry and dishwash detergent builder
  • Liquid industrial degreaser and alkaline cleaner
  • Food processing equipment CIP sequestrant
  • Dairy and beverage industry cleaning formulations
  • Metal surface cleaning and phosphating pre-treatment
  • Paint and pigment dispersant

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